Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

An excess of aqueous ammonia is introduced into a solution containing the complex ion $[\text{Co(H}_2\text{O})_6]^{2+}$. $[\text{Co(H}_2\text{O})_6]^{2+} + 6\text{NH}_3 \rightleftharpoons [\text{Co(NH}_3)_6]^{2+} + 6\text{H}_2\text{O}$.
(a)[1]

Complete the sentence so that it describes the colour change observed in this reaction. The colour changes from ................. to ................. .

(b)[1]

Write a formula for the stability constant, $K_{\text{stab}}$, of $[\text{Co(NH}_3)_6]^{2+}$.

(c)[1]

The value of $K_{\text{stab}}$ for $[\text{Co(NH}_3)_6]^{2+}$ is $7.7 \times 10^4$. What conclusion can be drawn about the properties of $[\text{Co(NH}_3)_6]^{2+}$ and $[\text{Co(H}_2\text{O})_6]^{2+}$ from this $K_{\text{stab}}$ value?

(d(i))[1]

Using the fact that $[\text{Co(NH}_3)_6]^{3+} + e^- \rightleftharpoons [\text{Co(NH}_3)_6]^{2+}$ has $E^{\circ} = +0.10\,\text{V}$, and the Data Booklet, calculate the $E^{\circ}_{\text{cell}}$ value for the oxidation of $[\text{Co(NH}_3)_6]^{2+}$.

(d(ii))[1]

Write an ionic equation for the oxidation of $[\text{Co(NH}_3)_6]^{2+}$.

(d(iii))[2]

Predict, by selecting suitable data from the Data Booklet, whether oxygen can oxidise $\text{Co}^{2+}(aq)$ in acidic solution when ammonia is absent. Explain your answer.

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