Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

Manganese, chromium and ruthenium all belong to the transition elements.
(a)[1]

Explain the meaning of the term transition element.

(b(i))[1]

Describe the colour change observed when excess of $\text{Sn}^{2+}(aq)$ is added separately to dilute acidified $\text{MnO}_4^{-}(aq)$ and to dilute acidified $\text{Cr}_2\text{O}_7^{2-}(aq)$.

(b(ii))[1]

Write an equation showing the reaction of $\text{Sn}^{2+}(aq)$ with acidified $\text{Cr}_2\text{O}_7^{2-}(aq)$.

(c(i))[1]

State the meaning of a co-ordination number of six.

(c(ii))[1]

State the formula for $X$. Be sure to include its charge.

(c(iii))[3]

Draw the two isomeric forms of $X$. Your diagrams should show the three-dimensional shapes of the two isomers and how each ligand is attached to the central ruthenium ion.

(c(iv))[1]

Suggest which type of isomerism is shown by $X$.

(c(v))[3]

Explain how colour arises in a transition element complex such as $X$.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: Produces one or more stable ions with a partially filled d-subshell

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