Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

Ethanedioate ions, $\text{C}_2\text{O}_4^{2-}$, serve as bidentate ligands.
(a)[1]

Explain what the term ligand means.

(b)[2]

$\text{Cr}^{3+}(aq)$ and $\text{C}_2\text{O}_4^{2-}(aq)$ ions combine to form the complex ion $[\text{Cr}(\text{C}_2\text{O}_4)_2(\text{H}_2\text{O})_2]^-$. Draw two stereoisomers of this complex ion. You may use a diagram to show $\text{C}_2\text{O}_4^{2-}$.

(c(i))[2]

The solubility of calcium ethanedioate, $\text{CaC}_2\text{O}_4$, is $6.65 \times 10^{-3}\,\text{g dm}^{-3}$ at $298\,\text{K}$. Write an expression for the solubility product, $K_{sp}$, of $\text{CaC}_2\text{O}_4$. State the units.

(c(ii))[2]

Calculate the numerical value of $K_{sp}$ for $\text{CaC}_2\text{O}_4$ at $298\,\text{K}$. Give your answer in standard form to two significant figures.

Worked solution & mark scheme

This 7-mark question has a full step-by-step worked solution and mark scheme. One marking point: A species that donates a lone pair to a central metal atom or ion to form a dative bond

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