Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a)[2]

Complete the electronic configurations for Cu and $\text{Cu}^{2+}$.

(b(i))[1]

The $3d$ orbitals in an isolated $\text{Cu}^{2+}$ ion are degenerate. Explain what is meant by degenerate in this situation.

(b(ii))[1]

Complete the diagram showing the splitting of the $3d$ orbital energy levels in an octahedral complex.

(c(i))[1]

1,2-diaminoethane, $\text{H}_2\text{NCH}_2\text{CH}_2\text{NH}_2$, $en$, acts as a bidentate ligand. Explain what is meant by bidentate.

(c(ii))[2]

The $\text{Cu}^{2+}$ ion and $en$ form the complex ion $[\text{Cu}(en)_3]^{2+}$. Draw the two optical isomers of this complex ion. You may use the given representation to show $en$.

Worked solution & mark scheme

This 7-mark question has a full step-by-step worked solution and mark scheme. One marking point: Correct electron configuration for Cu: $[\mathrm{Ar}]3d^{10}4s^1$

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