Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a)[2]

Complete the electron arrangements for Ni and $\text{Ni}^{2+}$.

(b(i))[1]

In an isolated transition metal atom or ion, the d orbitals all have identical energy. What term is used for orbitals with the same energy level?

(b(ii))[2]

Complete the diagram to illustrate the splitting of the d orbital energy levels in an octahedral complex ion.

(b(iii))[4]

On the axes below, sketch the shape of one d orbital from the lower energy level and one d orbital from the higher energy level.

(c)[3]

The octahedral complex $[\text{Ni(H}_2\text{O)}_6]^{2+}$ appears green. Explain the source of the colour of this complex.

(d)[4]

When $\text{NH}_3(aq)$ is added to the green solution containing $[\text{Ni(H}_2\text{O)}_6]^{2+}$, a grey-green precipitate, A, appears. On adding excess $\text{NH}_3(aq)$, this precipitate dissolves to form a blue-violet solution, B. Suggest formulae for A and B and write equations for the two reactions leading to A and B.

Worked solution & mark scheme

This 16-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate electronic configurations/orbital box diagrams for Ni and Ni$^{2+}$

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