Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a)[2]

Complete the electron configurations of Ni and $\text{Ni}^{2+}$.

(b(i))

The $d$ orbitals in an isolated transition metal atom or ion all have the same energy. What name is given to orbitals with equal energy?

(b(ii))

Complete the diagram to show how the $d$ orbital energy levels split in an octahedral complex ion.

(b(iii))[4]

On the axes below, sketch the shapes of one $d$ orbital from the lower-energy level and one $d$ orbital from the higher-energy level.

(c)[3]

The octahedral complex $[\text{Ni(H}_2\text{O)}_6]^{2+}$ is green. Explain where the colour of this complex comes from.

(d)[4]

When $\text{NH}_3\text{(aq)}$ is added to the green solution containing $[\text{Ni(H}_2\text{O)}_6]^{2+}$, a grey-green precipitate, A, forms. This precipitate dissolves in excess $\text{NH}_3\text{(aq)}$ to produce a blue-violet solution, B. Suggest formulae for A and B, and write equations for the two reactions that form A and B.

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