Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a)[1]

State any two common chemical properties of a transition element.

(b(i))[1]

Aqueous solutions of cobalt(II) salts contain the complex ion $[\text{Co}(\text{H}_2\text{O})_6]^{2+}$. What is meant by complex ion?

(b(ii))[4]

Separate samples of $[\text{Co}(\text{H}_2\text{O})_6]^{2+}$ are each treated with excess aqueous ammonia, excess concentrated HCl and excess aqueous sodium hydroxide, as shown in Fig. 2.1. Complete Table 2.1 to show the reactions of $[\text{Co}(\text{H}_2\text{O})_6]^{2+}$. For every reagent, state the formula of the cobalt species formed, the colour and physical state of the cobalt species formed, and the reaction type.

(c(i))[2]

Explain what is meant by a bidentate ligand.

(c(ii))[3]

The complex $\left[\text{Co(H}_2\text{O)}_2(\text{C}_2\text{O}_4)\text{BrCl}\right]^-$ shows stereoisomerism. Complete the three-dimensional diagrams in Fig. 2.2 to display four stereoisomers of $\left[\text{Co(H}_2\text{O)}_2(\text{C}_2\text{O}_4)\text{BrCl}\right]^-$.

(c(iii))[1]

State the oxidation state of cobalt in this complex and name a type of stereoisomerism shown.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: Transition metals display variable oxidation states

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