Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a)[2]

The $3d$ orbitals of an isolated $\text{Fe}^{2+}$ ion are degenerate. Finish the diagram to illustrate how the $3d$ orbital energy levels split first in an isolated $\text{Fe}^{2+}$ ion and then when $\text{Fe}^{2+}$ forms an octahedral complex.

(b(i))[2]

Bipyridine, bipy, acts as a bidentate ligand. Explain what is meant by bidentate ligand.

(b(ii))[3]

Complete the three-dimensional diagrams to show the two stereoisomers of $[\text{Fe(bipy)}_3]^{2+}$. State the type of stereoisomerism shown. Use the symbol given to represent bipy in your diagrams.

(c)[1]

Use suitable data from Table 4.1 to state which iron(III) complex is hardest to reduce. Explain your answer.

(d)[3]

Using the hybridisation of the carbon atoms and the nitrogen atom, and orbital overlap, suggest how the $\sigma$ and $\pi$ bonds form in a pyridine molecule.

(e)[3]

Complete the diagram to show the mechanism for the reaction of pyridine with $\text{Cl}^+$. Include every relevant charge, dipole, lone pair of electrons and curly arrow as appropriate.

Worked solution & mark scheme

This 14-mark question has a full step-by-step worked solution and mark scheme. One marking point: Five $3d$ orbitals separate into two higher-energy and three lower-energy orbitals in a complex

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