Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a)[1]

Explain why transition elements exhibit variable oxidation states.

(b)[1]

Sketch the shape of a $3d_{xy}$ orbital.

(c)[3]

Explain why transition elements produce coloured compounds.

(d(i))[1]

State the colour shown by $\text{Cu(OH)}_2(s)$ and by $[\text{Cu(NH}_3)_4(\text{H}_2\text{O})_2]^{2+}(aq).

(d(ii))[1]

Use Le Chatelier’s principle to explain why a precipitate appears when $\text{NaOH}(aq)$ is added dropwise to $[\text{Cu(H}_2\text{O})_6]^{2+}(aq)$.

(e)[2]

The formula $[\text{Cu(NH}_3)_4(\text{H}_2\text{O})_2]^{2+}$ can exist as two stereoisomers. Draw three-dimensional diagrams to show the two stereoisomers.

Worked solution & mark scheme

This 9-mark question has a full step-by-step worked solution and mark scheme. One marking point: The d and s orbitals lie very close together in energy.

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