Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a)[1]

Define the term transition element.

(b)[1]

Sketch the form of a $3d_{z^2}$ orbital.

(c(i))[1]

Explain the meaning of a heterogeneous catalyst.

(c(ii))[3]

Describe how a heterogeneous catalyst works in a reaction.

(d)[2]

Write equations for both reactions described below. Reaction 1: Manganese(VII) oxide, $\text{Mn}_2\text{O}_7$, is formed when $\text{KMnO}_4$ is treated with concentrated sulfuric acid. Reaction 2: $\text{Mn}_2\text{O}_7$ breaks down to give manganese(IV) oxide and a colourless diatomic gas.

(e(i))[2]

Write the ionic equation, and state the type of reaction, for the reaction of $[\text{Mn(H}_2\text{O})_6]^{2+}$ with $\text{NaOH}(aq)$.

(e(ii))[2]

Write the ionic equation, and state the type of reaction, for the reaction of $[\text{Mn(H}_2\text{O})_6]^{2+}$ with concentrated $\text{HCl}$.

(e(iii))[1]

Suggest the formula of the manganese species formed when $\text{Mn}^{2+}(aq)$ reacts with $\text{Cl}_2$. State the reaction type.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: gives one or more stable ions/compounds/oxidation states with incomplete (partially filled) $(3)d$ orbitals

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI