Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

EDTA$^{4-}$ is an example of a polydentate ligand.
(a(i))[2]

Explain what is meant by the term polydentate ligand.

(a(ii))[1]

When EDTA$^{4-}$ is added to a solution of $[\text{Cd(H}_2\text{O)}_6]^{2+}$, a new complex, $[\text{CdEDTA}]^{2-}$, is formed. Equilibrium 1 is: $[\text{Cd(H}_2\text{O)}_6]^{2+} + \text{EDTA}^{4-} \rightleftharpoons [\text{CdEDTA}]^{2-} + 6\text{H}_2\text{O}$. On the EDTA$^{4-}$ structure, circle the six atoms that bond with the metal ion.

(a(iii))[2]

Write an expression for the stability constant, $K_{\text{stab}1}$, for equilibrium 1, and give its units.

(b(i))[1]

$K_{\text{eq}4}$ is the equilibrium constant for equilibrium 4. Write it in terms of $K_{\text{stab}2}$ and $K_{\text{stab}3}$.

(b(ii))[2]

Calculate the value of the standard Gibbs free energy change, $\Delta G^\circ$, for equilibrium 4 at $298\,\text{K}$.

(b(iii))[1]

State how $\Delta G^\circ$ changes as the temperature rises. Explain your answer.

Worked solution & mark scheme

This 9-mark question has a full step-by-step worked solution and mark scheme. One marking point: a species that can donate/use more than one lone pair, or several lone pairs

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