Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a(i))[1]

Complete these electronic configurations: cobalt atom, $\text{Co}$: $1s^22s^22p^6\,\ldots$ ; cobalt(II) ion, $\text{Co}^{2+}$: $1s^22s^22p^6\,\ldots$.

(a(ii))[5]

State the colours seen when concentrated $\text{HCl(aq)}$ is added to an aqueous solution of cobalt(II) nitrate, $\text{Co(NO}_3)_2$. Give the formulae and geometry of the complexes produced.

(b)[3]

The formula $\text{Ni(R}_3\text{P)}_2\text{I}_2$ has two isomers, whereas $\text{Co(R}_3\text{P)}_2\text{I}_2$ has only one structure. ($\text{R}$ = alkyl, $\text{R}_3\text{P}$ is a monodentate ligand.) Draw the structure of $\text{Co(R}_3\text{P)}_2\text{I}_2$ and both isomers of $\text{Ni(R}_3\text{P)}_2\text{I}_2$.

Worked solution & mark scheme

This 9-mark question has a full step-by-step worked solution and mark scheme. One marking point: Cobalt electronic arrangement: $\text{Co}: \ldots 3s^2 3p^6 3d^7 4s^2$ and $\text{Co}^{2+}: \ldots 3s^2 3p^6 3d^7$

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI