Chemistry 9701 · AS & A Level · Chemistry of transition elements

Chemistry of transition elements — practice question

(a(i))

In the diagrams below, indicate the outer electron arrangements of the atoms and ions shown. (Use the symbol $\uparrow\downarrow$ to show two electrons paired in one orbital.)

(a(ii))[4]

Use the diagrams above to account for why $\text{Fe}^{2+}$(aq) ions are coloured, whereas $\text{Zn}^{2+}$(aq) ions are colourless.

(b(i))

When concentrated $\text{HCl}$ is added to a solution of $\text{Cu}^{2+}$(aq) ions, the solution becomes yellow. State the formula of the species responsible for the yellow colour and name the type of reaction that has taken place.

(b(ii))[7]

Ammonia may behave either as a base or as a ligand. Describe the colour changes observed as $\text{NH}_3$(aq) is added gradually, with stirring, to the yellow solution, until $\text{NH}_3$(aq) is in excess. Identify the three ions or compounds responsible for the new colours.

(c(i))

When aqueous solutions of $\text{KI}$ and $\text{K}_2\text{S}_2\text{O}_8$ are mixed, almost no reaction happens at first, but when a few drops of $\text{Fe}^{2+}$(aq) or $\text{Fe}^{3+}$(aq) are added, iodine, $\text{I}_2$(aq), is produced at a steady rate. Write an equation for the overall reaction.

(c(ii))

State the exact role of the iron ions in this reaction.

(c(iii))[3]

By means of equations or otherwise, explain why the presence of either $\text{Fe}^{2+}$ or $\text{Fe}^{3+}$ can speed up the reaction.

Worked solution & mark scheme

This 14-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate electron configuration diagrams for Fe and Fe$^{2+}$ or Zn$^{2+}$, with 4s and 3d electrons displayed

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