Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

Potassium chloride, $\text{KCl}$, and magnesium chloride, $\text{MgCl}_2$, are ionic solids. Table 1.1 lists the standard enthalpy changes of solution, the lattice energies, and the standard enthalpy changes of hydration.
(a)[2]

Complete the energy cycle for the enthalpy change of solution and the lattice energy of potassium chloride, $\text{KCl}$, together with the relevant enthalpy changes of hydration. Add a label to your diagram. State symbols must be shown.

(b)[2]

Using the information in Table 1.1, calculate the enthalpy change of hydration of magnesium ions, $\text{Mg}^{2+}$. Show your working.

(c)[2]

Explain why the lattice energy of $\text{MgCl}_2$ is more exothermic than the lattice energy of $\text{KCl}$.

(d(i))[1]

Define the term enthalpy change of atomisation.

(d(ii))[1]

Define the term first electron affinity.

(e(i))[1]

Explain what is meant by entropy, $S$.

(e(ii))[1]

Potassium chloride is very soluble in water at $20\,^{\circ}\text{C}$. Explain the solubility of potassium chloride with reference to change in entropy, $\Delta S$.

(e(iii))[1]

Use the Gibbs equation and your answer to part (e)(ii) to predict whether potassium chloride is more soluble in water at $20\,^{\circ}\text{C}$ or at $80\,^{\circ}\text{C}$. Explain your answer.

Worked solution & mark scheme

This 11-mark question has a full step-by-step worked solution and mark scheme. One marking point: gaseous $\mathrm{K^+(g)}$ and $\mathrm{Cl^-(g)}$ ions AND aqueous $\mathrm{KCl(aq)}$ or $\mathrm{K^+(aq) + Cl^-(aq)}$

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