Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

(a)[2]

Define electron affinity.

(b)[1]

Write the equation for calcium’s second ionisation energy process. Include state symbols.

(c)[3]

Oxygen is present as $\text{O}_2$ molecules. Use the information provided here to calculate the bond energy of the $\text{O} = \text{O}$ bond. Show your working clearly.

(d(i))[1]

Suggest why oxygen’s first electron affinity is negative.

(d(ii))[1]

Suggest why oxygen’s second electron affinity is positive.

(e)[2]

Calculate the enthalpy of formation for calcium oxide, $\text{CaO(s)}$.

(f)[2]

The lattice energy of lithium fluoride, $\text{LiF(s)}$, is $-1022\,\text{kJ mol}^{-1}$.\n\nIdentify the factor that makes the lattice energy of calcium oxide more exothermic than that of lithium fluoride. Explain why this factor leads to the difference in lattice energies.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: A change in enthalpy / energy

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