Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

(a)[2]

What does the term electron affinity mean?

(b)[1]

Write the equation for the process that represents the second ionisation energy of calcium. Include state symbols.

(c)[3]

Oxygen is present as $\text{O}_2$ molecules. Use the information provided to calculate the bond energy of the $\text{O=O}$ bond. Show your working.

(d(i))[1]

Suggest why oxygen has a negative first electron affinity.

(d(ii))[1]

Suggest why the second electron affinity of oxygen is positive.

(e)[2]

Calculate the enthalpy of formation for calcium oxide, $\text{CaO(s)}$.

(f)[2]

The lattice energy of lithium fluoride, $\text{LiF(s)}$, is $-1022\,\text{kJ mol}^{-1}$. Identify the factor that makes the lattice energy of calcium oxide more exothermic than that of lithium fluoride. Explain why this factor leads to the difference in lattice energies.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: a change in enthalpy OR a change in energy

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