Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

(a(i))[2]

Define the term lattice energy, $\Delta H_{\text{latt}}$.

(a(ii))[1]

Define the enthalpy change of solution, $\Delta H_{\text{sol}}$.

(b)[1]

The enthalpy change of hydration may be written as $\Delta H_{\text{hyd}}$. Write the mathematical expression for the $\Delta H_{\text{sol}}$ of NaCl in terms of $\Delta H_{\text{latt}}(\text{NaCl})$, $\Delta H_{\text{hyd}}(\text{Na}^+)$ and $\Delta H_{\text{hyd}}(\text{Cl}^-)$.

(c)[3]

Complete the Born-Haber cycle in Fig. 8.1 for the ionic solid NaCl. Add the state symbols for the relevant species.

(d)[2]

Predict which ion, $\text{Cl}^-$ or $\text{NO}_3^-$, has the more negative enthalpy change of hydration. Explain your reasoning.

Worked solution & mark scheme

This 9-mark question has a full step-by-step worked solution and mark scheme. One marking point: Energy change that occurs when 1 mole of an ionic solid is formed

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