Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

(a(i))[2]

What does first electron affinity mean?

(a(ii))[1]

The first electron affinity of an atom is usually exothermic, but the second electron affinity is endothermic. Suggest why.

(a(iii))[2]

Describe the overall trend in first electron affinities for $\text{Cl}$, $\text{Br}$ and $\text{I}$. Explain your answer.

(b)[3]

Calculate the first electron affinity for iodine. Use the relevant data from Table 3.1 in your working. Drawing a labelled energy cycle may help. Show all working.

(c)[1]

Predict how $\Delta H^\circ_{\text{latt}}$ of $\text{CdI}_2(s)$ compares with $\Delta H^\circ_{\text{latt}}$ of $\text{ZnI}_2(s)$. Put a tick (✓) in the correct box in Table 3.2. Explain your answer.

(d)[1]

Predict how $\Delta H^{\ominus}_{\text{latt}}$ of $\text{CdI}_2(s)$ compares with $\Delta H^{\ominus}_{\text{latt}}$ of $\text{ZnI}_2(s)$. Put a tick (✓) in the correct box in Table 3.2. Explain your answer.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: enthalpy or energy change

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