Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

Sodium oxide, $\text{Na}_2\text{O}$, is a white crystalline solid and has a high melting point.
(a)[2]

Write an equation for the reaction between sodium and oxygen to make sodium oxide. Include state symbols.

(b)[2]

Explain why the melting point of sodium oxide is high.

(c(i))[2]

Explain why the solution formed is alkaline. Your answer should make use of the Brønsted-Lowry theory of acids and bases.

(c(ii))[3]

Calculate the pH of the solution formed when $3.10\,\text{g}$ of sodium oxide are added to $400\,\text{cm}^3$ of water.

(d)[4]

Use the data below, together with any other appropriate data from the Data Booklet, to find the lattice energy of sodium oxide, $\Delta H_{\text{latt}}^\circ\,\text{Na}_2\text{O(s)}$.

(e)[2]

State how $\Delta H_{\text{latt}}^\circ\,\text{Na}_2\text{S(s)}$ compares with $\Delta H_{\text{latt}}^\circ\,\text{Na}_2\text{O(s)}$. Show this by placing a tick ($\checkmark$) in the correct box in the table. Explain your answer.

Worked solution & mark scheme

This 15-mark question has a full step-by-step worked solution and mark scheme. One marking point: $4Na(s) + O_2(g) \to 2Na_2O(s)$ balanced with every formula correct

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