Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

(a(i))[1]

What does the term enthalpy change of hydration, $\Delta H^{\circ}_{\text{hyd}}$, mean?

(a(ii))[1]

Write an equation to show the $\Delta H^{\circ}_{\text{hyd}}$ of the $\text{Mg}^{2+}$ ion.

(a(iii))[1]

Suggest a reason why $\Delta H^{\circ}_{\text{hyd}}$ of the $\text{Mg}^{2+}$ ion is greater than $\Delta H^{\circ}_{\text{hyd}}$ of the $\text{Ca}^{2+}$ ion.

(a(iv))[2]

Suggest why it is impossible to determine the enthalpy change of hydration of the oxide ion, $\text{O}^{2-}$.

(b)[4]

The enthalpy change of solution for $\text{MgCl}_2$, $\Delta H^{\circ}_{\text{sol}}(\text{MgCl}_2(s))$, is represented by the following equation: $\text{MgCl}_2(s) + \text{aq} \rightarrow \text{Mg}^{2+}(aq) + 2\text{Cl}^-(aq)$. Describe the simple apparatus you could use, and the measurements you would make, in order to determine a value for $\Delta H^{\circ}_{\text{sol}}(\text{MgCl}_2(s))$ in the laboratory.

(c(i))[2]

By constructing relevant thermochemical cycles, use the above data to calculate a value for $\Delta H^{\circ}_{\text{sol}}(\text{MgCl}_2(s))$.

(c(ii))[1]

By constructing relevant thermochemical cycles, use the above data to calculate a value for $\Delta H^{\circ}_{\text{hyd}}(\text{Cl}^-(g))$.

(d)[4]

Describe and explain how the solubility of magnesium sulfate compares to that of barium sulfate.

Worked solution & mark scheme

This 16-mark question has a full step-by-step worked solution and mark scheme. One marking point: Energy/enthalpy change released when $1\ \text{mol}$ of ions in the gas phase are dissolved in water

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