Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

(a(i))

What does the term lattice energy mean?

(a(ii))[3]

Write an equation to show the lattice energy of MgO.

(b)[3]

The apparatus shown in the diagram can be used to measure the enthalpy change of formation of magnesium oxide, $\Delta H_f^\circ(\text{MgO})$. State the measurements you would need to take with this apparatus in order to calculate $\Delta H_f^\circ(\text{MgO})$.

(c)[3]

Using the data below, together with suitable data from the Data Booklet, calculate a value of $\Delta H_f^\circ(\text{MgO})$. Lattice energy of $\text{MgO(s)} = -3791\ \text{kJ mol}^{-1}$ Enthalpy change of atomisation of Mg $= +148\ \text{kJ mol}^{-1}$ Electron affinity of the oxygen atom $= -141\ \text{kJ mol}^{-1}$ Electron affinity of the oxygen anion, $\text{O}^- = +798\ \text{kJ mol}^{-1}$

(d)[3]

Write equations, including state symbols, for any reactions of the two oxides below with water. Then suggest pH values for the solutions formed. Oxides: $\text{Na}_2\text{O}$ and $\text{MgO}$.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: The enthalpy change given out when 1 mole is formed

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