Chemistry 9701 · AS & A Level · Chemical energetics

Chemical energetics — practice question

V and W are elements that sit in neighbouring groups of the Periodic Table. V reacts with oxygen to produce an acidic gas, X. V also forms an anion with formula $\text{VO}_m^-.$ W reacts with oxygen to produce an acidic gas, Y. W also forms an anion with formula $\text{WO}_n^{2-}.$ A solution of $\text{WO}_n^{2-}$ gives a white precipitate with $\text{Ba}^{2+}(aq)$ but there is no visible change with $\text{Mg}^{2+}(aq)$.
(a)[3]

Fill in the table below.

(b)[3]

Using enthalpy changes, explain why $\text{WO}_n^{2-}$ gives a white precipitate with $\text{Ba}^{2+}(aq)$ but produces no visible change with $\text{Mg}^{2+}(aq)$.

Worked solution & mark scheme

This 6-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate identities for V, X, m, W, Y and n

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