Chemistry 9701 · AS & A Level · Carboxylic acids and derivatives

Carboxylic acids and derivatives — practice question

The displayed structure of glycolic acid is shown.
(a)[4]

Complete the table to show the observations when an aqueous solution of glycolic acid is added separately to each reagent. If a reaction takes place, name the functional group in glycolic acid that is responsible. The reagents are $\text{Na}_2\text{CO}_3(\text{aq})$, 2,4-DNPH, and acidified $\text{Cr}_2\text{O}_7^{2-}$.

(b(i))[1]

Two routes for making glycolic acid are shown. Sequence A: $\text{HCHO} \\ \xrightarrow[{\text{HCN and NaCN}}]{\text{reaction 1}} X \\ \xrightarrow[ ]{\text{reaction 2}} \\ \text{CH}_2(\text{OH})\text{CO}_2\text{H}$. Sequence B: $\text{CH}_3\text{CO}_2\text{H} \\ \xrightarrow[ ]{\text{Br}_2, \text{reaction 3}} \\ \\ \text{CH}_2\text{BrCO}_2\text{H} \\ \xrightarrow[ ]{\text{reaction 4}} \\ \\ \text{CH}_2(\text{OH})\text{CO}_2\text{H}$. Draw the structure of $X$.

(b(ii))[1]

Name the reagent used in reaction 2.

(b(iii))[1]

Name the mechanism for reaction 3.

(b(iv))[1]

Suggest the essential condition for reaction 3.

(b(v))[2]

Reaction 4 proceeds through an $\text{S}_\text{N}2$ mechanism. Complete the mechanism diagram for reaction 4. Include every relevant charge, partial charge, curly arrow and lone pair.

(c(i))[1]

State the role played by $\text{NaBH}_4$ in this reaction.

(c(ii))[2]

Write the equation for this reaction in molecular formulae. Use $[\text{H}]$ to stand for $\text{NaBH}_4$.

(d(i))[2]

The infra-red spectrum of $Y$ is shown. State one way in which this spectrum differs from the infra-red spectrum of glycolic acid. Explain your answer with specific reference to the peaks in the range $1500$-$4000\ \text{cm}^{-1}$.

(d(ii))[2]

Suggest a structure for $Y$.

Worked solution & mark scheme

This 17-mark question has a full step-by-step worked solution and mark scheme. One marking point: Fizzing with $Na_2CO_3$

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