Chemistry 9701 · AS & A Level · Carboxylic acids and derivatives

Carboxylic acids and derivatives — practice question

A reaction sequence based on propanoic acid is shown. $\text{CH}_3\text{CH}_2\text{CO}_2\text{H}$ undergoes reaction 1 to give $\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}$. In reaction 2, $\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}$ is changed back into $\text{CH}_3\text{CH}_2\text{CO}_2\text{H}$. Propanoic acid reacts with $\text{CaCO}_3$ to produce three substances. Reaction 3 converts $\text{CH}_3\text{CH}_2\text{CH}_2\text{OH}$ into $\text{CH}_3\text{CO}_2\text{CH}_2\text{CH}_2\text{CH}_3$.
(a)[2]

Write an equation for reaction 1, with $[\text{H}]$ representing the reducing agent.

(b(i))[1]

What sort of reaction is reaction 2?

(b(ii))[2]

Suggest a suitable reagent and conditions for reaction 2.

(c)[2]

Write an equation for the reaction between propanoic acid and calcium carbonate, $\text{CaCO}_3$.

(d(i))[2]

Suggest a suitable reagent and conditions for reaction 3.

(d(ii))[1]

Which other product is formed in reaction 3?

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: Balanced equation: $\mathrm{CH_3CH_2CO_2H + 4[H] \rightarrow CH_3CH_2CH_2OH + H_2O}$

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