Chemistry 9701 · AS & A Level · Carbonyl compounds

Carbonyl compounds — practice question

Lactones are cyclic esters. When the conditions are suitable, lactones can be produced from molecules containing both an alcohol and a carboxylic acid functional group. Equation 1 gives one example of lactone formation. Fig. 5.1 shows how lactone P is synthesised from compound M.
(a(i))[1]

M reacts with hot concentrated acidified $\text{KMnO}_4\text{(aq)}$ to form N, $\text{C}_6\text{H}_{10}\text{O}_3$, in reaction 1. Show the structure of N.

(a(ii))[1]

N is reduced by $\text{NaBH}_4$ to give 5-hydroxyhexanoic acid in reaction 2. Write an equation for reaction 2 using molecular formulae. In the equation, use $[\text{H}]$ to stand for one hydrogen atom supplied by the reducing agent.

(a(iii))[2]

Reaction 2 is a nucleophilic addition. Explain why reaction 2 produces a mixture of two organic compounds.

(a(iv))[1]

Draw lactone P, the product of reaction 3.

(b)[2]

A student follows the progress of reaction 2 by infrared spectroscopy. Use Table 5.1 to suggest why it is hard to distinguish between N and 5-hydroxyhexanoic acid using infrared spectroscopy.

(c)[2]

An unknown lactone Q is examined by mass spectrometry. Table 5.2 gives data from the mass spectrum. Use these data to deduce the structure of Q. Show your working.

Worked solution & mark scheme

This 9-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate displayed formula for $N$

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