Chemistry 9701 · AS & A Level · Atoms, molecules and stoichiometry

Atoms, molecules and stoichiometry — practice question

Fig. 5.1 shows the skeletal formula of W.
(a)[2]

W has two positional isomers. Only one exhibits stereoisomerism. Draw the structures of the two positional isomers of W in the boxes.

(b(i))[1]

Describe the origin of stereoisomerism in W.

(b(ii))[1]

State why W shows stereoisomerism but one of the positional isomers in (a) does not.

(c)[1]

Draw the skeletal structure of W's stereoisomer.

(d(i))[1]

W reacts with reagent X to give ethanoic acid and pentanoic acid. State the role of X in this reaction.

(d(ii))[1]

Identify X and state the conditions used for this reaction.

Worked solution & mark scheme

This 7-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate skeletal structure for alkene

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