Chemistry 9701 · AS & A Level · Atoms, molecules and stoichiometry

Atoms, molecules and stoichiometry — practice question

Butanedioic acid is found in amber, algae, lichens, sugar cane and beets. It can be prepared in two stages starting from 1,2-dibromoethane. $\text{BrCH}_2\text{CH}_2\text{Br} \xrightarrow{\text{step 1}} X \xrightarrow{\text{step 2}} \text{HO}_2\text{CCH}_2\text{CH}_2\text{CO}_2\text{H}$ Which reagents could be used for this synthesis?

  • Astep 1: HCN(g); step 2: HCl(aq)
  • Bstep 1: HCO$_2$Na(aq); step 2: HCl(aq)
  • Cstep 1: KCN(aq/alcoholic); step 2: H$_2$SO$_4$(aq)
  • Dstep 1: NaOH(aq); step 2: K$_2$Cr$_2$O$_7$/H$_2$SO$_4$(aq)

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