Chemistry 9701 · AS & A Level · Atoms, molecules and stoichiometry

Atoms, molecules and stoichiometry — practice question

Isomerism is found in many organic compounds. Its two chief types are structural isomerism and stereoisomerism.
(a(i))[1]

Explain what structural isomerism means.

(a(ii))[2]

State two different molecular features that can produce stereoisomerism.

(b)[1]

Give the structural formula of the organic compound formed when tartaric acid, $\text{HO}_2\text{CCH(OH)CH(OH)CO}_2\text{H}$, is treated with excess $\text{NaHCO}_3$.

(c)[1]

Does citric acid exhibit optical isomerism? Explain your answer.

(d(i))

Show, by calculation, that the empirical formula for $W$ is $\\text{C}_4\\text{H}_6\\text{O}_5$.

(d(ii))[3]

Given that the $M_r$ of $W$ is $134$, use this to work out the molecular formula of $W$.

(e(i))

Use these data to determine how many carboxylic acid groups are in one molecule of $W$.

(e(ii))[5]

Suggest the displayed formula of $W$.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: Identical molecular formula

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