Chemistry 9701 · AS & A Level · Analytical techniques

Analytical techniques — practice question

NMR spectroscopy and X-ray crystallography are two methods that use electromagnetic radiation to determine the structures of large molecules.
(a)[4]

For each technique, state the sub-atomic particle involved, and explain how that particle interacts with the radiation.

(b)

NMR spectra 1 and 2 were recorded before and after alcohol Y was oxidised to form compound Z.

(b(i))

State which spectrum, 1 or 2, was produced by the alcohol, and give a reason for your choice.

(b(ii))

The mass spectrum for Y gave an $M : M+1$ peak ratio of $17.6 : 0.6$. Use this, together with the other information in the question, to propose the identities of both Y and Z.

(b(iii))

In the box provided, draw the displayed formula of $Y$.

(b(iv))

Explain why the NMR spectrum of $Z$ displays only one peak.

Worked solution & mark scheme

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