Chemistry 9701 · AS & A Level · An introduction to AS Level organic chemistry

An introduction to AS Level organic chemistry — practice question

(a) Here is a list of species that are able to react with organic compounds. $\text{CN}^-$, $\text{HCl}$, $\text{Cl}^-$, $\text{H}_2\text{O}$, $\text{CO}_3^{2-}$
(a(i))[1]

From the list, identify a species able to react with ethane.

(a(ii))[1]

From the list, identify two species able to attack the $\pi$ bond in ethene.

(a(iii))[2]

From the list, identify a species that can distinguish between solutions of propanoic acid and propan-1-ol. Describe any observations that occur.

(b(i))[1]

$\text{Cl(g)}$ can be produced from $\text{Cl}_2\text{(g)}$. State the conditions needed for this conversion.

(b(ii))[1]

Name the process.

(c(i))[1]

Name an organic functional group that reacts with a nucleophile in an addition reaction.

(c(ii))[1]

Name an organic functional group that tends to react with a nucleophile by an $\text{S}_\text{N}1$ substitution mechanism.

(d(i))[2]

But-1-ene reacts with steam in the presence of concentrated phosphoric acid to produce two isomers with molecular formula $\text{C}_4\text{H}_{10}\text{O}$. The two reactions proceed through different intermediate ions. Draw the structure of both intermediate ions.

(d(ii))[2]

Circle the more stable intermediate ion shown in (d)(i). Explain your answer.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: The species is chlorine, $Cl$.

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