Chemistry 9701 · AS & A Level · 4.1

4.1 — practice question

Both aluminium oxide, $\text{Al}_2\text{O}_3$, and phosphorus(V) oxide, $\text{P}_4\text{O}_{10}$, can be used as reagents and catalysts.
(a)[3]

The melting point of $\text{Al}_2\text{O}_3$ is $2072^\circ\text{C}$. The melting point of $\text{P}_4\text{O}_{10}$ is $340^\circ\text{C}$. Explain why these two compounds have different melting points.

(b(i))[1]

A $5.00\,\text{dm}^3$ sealed flask contains $0.400\,\text{mol}$ of CO(g) and $0.800\,\text{mol}$ of $\text{H}_2$(g) together with an $\text{Al}_2\text{O}_3$ catalyst. The flask is heated to a temperature of $290^\circ\text{C}$ and left until equilibrium is reached. Equation 1 shows the reaction. $\text{CO(g)} + 2\text{H}_2\text{(g)} \rightleftharpoons \text{CH}_3\text{OH(g)}$ The equilibrium constant, $K_c$, for equation 1 is given. $K_c = \dfrac{[\text{CH}_3\text{OH}]}{[\text{CO}][\text{H}_2]^2}$ State the units of $K_c$.

(b(ii))[3]

At equilibrium, the mixture contains $0.280\,\text{mol}$ of $\text{CH}_3\text{OH(g)}$. Calculate the value of $K_c$. Give your answer to three significant figures.

(b(iii))[1]

State and explain what happens, if anything, to the value of $K_c$ when the overall pressure in the sealed flask is increased.

(c(i))[1]

$\text{P}_4\text{O}_{10}$ catalyses the reversible reaction of CO with $\text{H}_2$ to form $\text{CH}_3\text{OH}$. Equation 1: $\text{CO(g)} + 2\text{H}_2\text{(g)} \rightleftharpoons \text{CH}_3\text{OH(g)}$ $\text{P}_4\text{O}_{10}$ then acts as a dehydrating agent, causing $\text{CH}_3\text{OH}$ to form $\text{CH}_3\text{OCH}_3$. Explain how the presence of a catalyst affects a chemical reaction.

(c(ii))[1]

Construct an equation showing the dehydration of $\text{CH}_3\text{OH}$ to produce $\text{CH}_3\text{OCH}_3$.

(c(iii))[1]

Write an equation showing the reaction of $\text{P}_4\text{O}_{10}$ with an excess of water.

Worked solution & mark scheme

This 11-mark question has a full step-by-step worked solution and mark scheme. One marking point: Al2O3 is an ionic compound

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