Chemistry 9701 · AS & A Level · 3.2

3.2 — practice question

Thin-layer chromatography and gas/liquid chromatography can be used to separate a mixture into its separate components.
(a(i))[2]

Define the following chromatography terms: $R_f$ value; retention time.

(a(ii))[1]

All chromatography types use a stationary phase and a mobile phase. Fill in Table 6.1 with a description of each one.

(b)[1]

A mixture containing two substances A and B is analysed by thin-layer chromatography. The $R_f$ value of substance A is larger than that of substance B. Suggest why substance A has a larger $R_f$ value.

(c(i))[1]

The two isomeric compounds Y and Z are examined by proton ($^1\mathrm{H}$) NMR spectroscopy. Complete Table 6.2 to predict how many peaks will be seen in the proton ($^1\mathrm{H}$) NMR spectra of Y and Z.

(c(ii))[2]

State all the different splitting patterns seen in the proton ($^1\mathrm{H}$) NMR spectra for Y and Z.

Worked solution & mark scheme

This 7-mark question has a full step-by-step worked solution and mark scheme. One marking point: (Rf value) equals the distance moved by a component / spot / solute divided by the distance moved by the solvent

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